Peter Day's MOLECULES INTO MATERIALS: CASE STUDIES IN MATERIALS PDF

By Peter Day

ISBN-10: 9812700382

ISBN-13: 9789812700384

This essential quantity brings jointly for the 1st time a variety of his articles on these kind of themes, grouped based on subject matter. each one crew is prefaced through a quick creation for the overall reader, placing the articles into their context within the evolution of the topic and describing the highbrow situations within which each one venture used to be conceived and finished.

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Additional resources for MOLECULES INTO MATERIALS: CASE STUDIES IN MATERIALS CHEMISTRY - MIXED VALENCY, MAGNETISM AND SUPERCONDUCTIVITY

Example text

4 kK. 3 kK) of requires further discussion. 0 kK). 52 kK, the separations of the made. The spectral energy differences cannot be three peaks being near the ratio required by Fig. 6(a). compared quantitatively with the other data in The lowest-energy hand does not seem to be split Table 111, since only the room-temperature FeLeither in FeC14 or FeBr4-, so from the approximate spectrum is available. 35-kK band contains all the spin-orbit components of the second excited state from chloride components of T2(ti--t2e) and the group of three bands to iodide, in agreement with our detailed conclusions to higher energy comes from 6T2(t1-&2).

5) The separation between fl and both 2e and 4tz becomes smaller along the sequence Co( 11)> Ni( 11)> Fe(III)>Cu(II) for a given halogen. I t may he significant that there have been repor@ of the preparation of Fe14-, but not yet of Cu14". 3~ A. Hansen, Theoret. Chim. Acta (to be published). S. Dalton 2054 Electronic Spectra of Some Post-transition-metal Halide Complexes By P. Day * and R. H. Seal, University of Oxford, Inorganic Chemistry Laboratory, South Parks Road, Oxford OX1 3QR The electronic absorption spectra of tetrahalide complexes of Zn".

Nyholm, J. Chem. Sac. 1959, 3997. 7 14 393 Molecules into Materials SPECTRA OF TETRAHALIDE COMPLEXES form clear rigid glasses a t 7i°K," only ethanol sufficiently dissolved both the compounds and an excess of tetra-allrylammonium halide, required to suppress solvolysis. For each compound, spectra were measured at room temperature in ethanolic solution containing various concentrations of excess halide ion to discover the lowest concentration at which solvolysis was completely suppressed. Spectra were measured at 77°K in a VLT-2 cryostat containing a FM-01 cell, both made by Research and Industrial Instruments Company.

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MOLECULES INTO MATERIALS: CASE STUDIES IN MATERIALS CHEMISTRY - MIXED VALENCY, MAGNETISM AND SUPERCONDUCTIVITY by Peter Day


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